By Matsui H.
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Is there a correlation between crosslinking and thermal stability? in: S. Al-Malaika, A. A. , Specialty Polymer Additives: Principles and Application. Blackwell Science, Oxford, England, 2001, pp. 359–374. 21. E. Combustion of Polymer Materials. Carl Hanser Verlag, Munich, Germany, 1986, p. 149. 22. ; Costa, L. F. A. , Fire Retardancy of Polymeric Materials. Marcel Dekker, New York, 2000, pp. 245–284. 23. Georlette, P. R. Horrocks and D. , Fire Retardant Materials. Woodhead Publishing, Cambridge, England, 2001, pp.
It is generally accepted that phosphorus ﬂame retardants are signiﬁcantly more effective in oxygen- or nitrogen-containing polymers, which could be either heterochain polymers or polymers with these elements in pendant groups. Effective phosphorus ﬂame retardants are more speciﬁc than halogen-based products to certain polymers. 39 Upon further heating, phosphorylated cellulose undergoes thermal decomposition and a signiﬁcant amount of char is formed at the expense of combustible volatile products that would be produced by virgin cellulose.
99 The average size of the particles of these specially prepared hydroxides is in the range 100 to 300 nm and the authors qualify them as nanoﬁllers. Usually, no or very little advantage is seen with these nanoscale hydroxides in terms of the LOI and UL-94 tests, but some advantages are observed in cone calorimetry. 97 Even at relatively high loadings of the silica, only marginal improvement in LOI values was observed. A decrease in the heat release rate measured in cone calorimetry is the commonly seen advantage of nanoscale particles, including nanoclays (discussed in detail in other chapters).
A bound for the least Gaussian prime w with a by Matsui H.